JAROSITE AND ALUNITE CEMENTS IN JURRASIC SANDSTONES OF UTAH AND NEVADA A POTENTIAL ANALOG FOR STRATIFIED SULFATE DEPOSITS ON EARLY MARS T M McCollom1 and S L Potter McIntyre2 1LASP University of Colorado Boulder mccollom lasplorado edu 2Department of Geology Southern Illinois University
The adsorption of phosphorus onto calcined alunite has been studied Its equilibrium isotherm has been measured The isotherm was determined by shaking 1 0 g calcined alunite particle size range 90–150 μm with 100 mL phosphorus solution of initial concentrations from 0 5 to 2 5 mmol/L The water bath shaking a constant rate of 200 rpm was used and the temperature maintained at 298 ± 2 K
FIG I The Kagom6 net whose nodes are the octahedral centres in sheets of the alunite type Associated tetrahedra above or below the sheets are indicated The axes ax and a2 refer to the ortho hexagonal unit in Table IV b E and c E and h and c t
Alunite Schukow H Breitinger D K Zeiske T Kubanek F Mohr J Schwab R G 1999 Localization of hydrogen and content of oxonium cations in alunite via neutron diffraction Zeitschrift fur Anorganische und Allgemeine Chemie 625 1999 synthetic 0 293
I have found it highly advantageous for impure alunite ores to operate within the range of 750 C to 950 C The optimum temperatures and time for most efficient calcination varies in accordance with the impurities present in the ore I have found that for most impuree alunite ores a range of 775 to 900 C is most advantageous
temperatures between 200 and 300 C H O S isotopic signatures of alunite combined with mineralogical features from all the studied occurrences whatever their type show characteristics of
t h e r m a l s t a b i l i t y a l u n i t e 5 C SUPERGENE 10 5 5 0 5 10 15 20 25 30 0 Pyrite Alunite Barite Gypsum GYPSUM ALUNITE BARITE δ34SSO2 0/00 4 δ 34 S S 2 py velocities of parent fluids Some of the Preble Mountain alunites appear to be similar to the magmatic 0 /00 0 100 150 200 250 300 350 400 SALINITIES NOT MEASURED 5
In the solution environment alunite and natroalunite are able to form stably by the Al 3 hydrolysis precipitation process at a temperature of 200 C a pH value of 0 4 and a reaction time of 5 h When Al 3 was precipitated at a K/Al molar ratio of 1 the aluminum precipitation efficiency and the vanadium precipitation efficiency were 64 77
Alunite dissolution was less affected by pH 0 8 log units min to max than jarosite 2 5 log units variation with pH Comparable dissolution rates from previous studies of jarosite range from −7 5 to −9 1 for K jarosite Elwood Madden et al 2012 and from −6 6 to −7 4 for Na jarosite Zahrai et al 2013 Fig 2 Table 2 A comparison of dissolution rates between these three
Concasseur mobile Concasseur fixe Broyeur industriel Machine minière Capacité t/h concasseur 30 30 50 50 100 moulin 0 5 5
John H Dilles David A John in Encyclopedia of Geology Second Edition 2021 Time Scales The duration of hydrothermal systems forming epithermal gold silver deposits has been estimated from isotopic dating of hydrothermal minerals 40 Ar 39 Ar and K Ar dating of K bearing minerals such as adularia illite and alunite by dating pre and post ore rocks and from theoretical
Published data on enargite hosted fluid inclusions T h = 295 degrees 200 degrees C 4 2 wt NaCl equiv indicate that the temperature and salinity both decrease with increasing distance from the porphyry Epithermal ore consists of stage 1 euhedral pyrite enargite luzonite and subsequent stage 2 Au is accompanied by tetrahedrite
Rates of alkali exchange between alunite and water have been measured in hydrothermal experiments of 1 hour to 259 days duration at 150 to 400 C Examination of run products by scanning electron microscope indicates that the reaction takes place by dissolution reprecipitation This exchange is modeled with an empirical rate equation which assumes a linear decrease in mineral surface area with
No 2 SLANSKYALUNITE MINERALS WHITE ISLAND 289 TABLE I X raypowder diffraction data of natroalunite and alunite in four samples from White Island detailed sample localities are given in the text WI l WI 2 WI 3 WIdA I dA I dA I dA I hkl 5 699 17 5 698 12 5 692 11 5 688 17 101 5 575 9 5 570 10 003
A charge of alunite ore weighing about 200 grams was placed in a Vycor retort The retort was then placed in a preheated electric furnace the furnace lid was closed and the temperature raised to about 580 to about 600 C and held at this level for about 60 minutes During roasting the retort was rotated continuously at about one rpm and
for 4 h at 6000 C followed by air oxidation of the reduced calcine for 1 h at 6000 C This report presents design calculations schematic dia grams and discussions of the essential features of a proposed process research unit PRU a continuous 6 lb/h alunite shaft furnace for studying the process
30 2 4 1 30 Anhydrous Sulfates Containing Hydroxyl or Halogen 30 2 where A B 2 XO4 Zq 30 2 4 Alunite Group Alunite Subgroup High temperature Newly formed at a temperature less than 300C
is 4 9 at 150 C 3 7 at 200 C and 3 1 at 250 C and values for the analogous alunite natroalunite reaction are 2 56 at 250 C 1 73 at 350 C and –0 99 at 450 C These values indicate that partitioning of al kalis is similar for jarosite and alunite and that in creasing temperature favors the sodium end member for both phases
Part H evolution of the Rodalquilar caldera complex and associated gold alunite deposits J J Rytuba 1 A Arribas Jr 2 C G Cunningham 3 E H McKee 1 M H Podwysocki 3 J G Smith 1 Rue de la Loi 200 B 1049 Brussels Belgium Received December 1989/Accepted August 3 1990 Abstract The Rodalquilar caldera complex is located in
The roasted alunite is further subjected to thermal decomposition in a fluid bed at a temperature of from 540 to 560 C by exposure to reducing agents sulphur solar oil kerosene converted gas or generator gas the reaction proceeding by the following route R 2 SO 4 Al 2 SO 4 3 2Al 2 O 3 0 5C 2 H 4 R 2 SO 4 3Al 2 O 3 3SO 2 CO 2
Filter type Compatible HIFI item Comments Oil filter SO 10052 Diesel oil filter SN 55429 Primary air filter SA 10377 X2 Hydraulic filter SH 54038 RESERVOIR/TANK
ttydrometallurgy 27 1991 85 97 85 Elsevier Science Publishers B V Amsterdam Kinetic study on the precipitation of alunite from manganese sulphate solutions T H Tam and T Tran Department of Mineral Processing and Extractive Metallurgy School of Mines The University of New South Wales Kensington NSW 2033 Australia Received November 15 1989 revised version
A charge of alunite ore weighing about 200 grams was placed in a Vycor retort The retort was then placed in a preheated electric furnace the furnace lid was closed and the temperature raised to about 580 to about 600 C and held at this level for about 60 minutes During roasting the retort was rotated continuously at about one rpm and
high temperature 200–400 8C low pH b3 magmatic hydrothermal environment in which SO 4 2 forms along with H 2 S from the disproportionation of SO 2 during the condensation of a magmatic vapor plume Magmatic steam alunite forms from expanding SO 2 rich magmatic vapors that rise so rapidly that sulfur isotopic exchange between SO 4
F a u l t s t y p i c a l l y p r o v i d e t h e f o c u s f o r f l u i d s t o m i g r a t e At the lowest temperature <200 C the alunite dissolves leaving residual silica at high
Alunite Schukow H Breitinger D K Zeiske T Kubanek F Mohr J Schwab R G Zeitschrift fur Anorganische und Allgemeine Chemie 625 1999 Localization of hydrogen and content of oxonium cations in alunite via neutron diffraction Locality synthetic Sample T = 2 K database code amcsd 6 943 6 943 17 227 90 90 120 R 3m
Alunite Ultrafine Powder Grinding Mill Alunite ultrafine powder grinding mill is an efficient industrial grinding mill It can grind alunite into fine powder meshes What s more it can also grind more than 100 kinds of non metallic ores
Postmineral alunite ± jarosite were previously interpreted to be supergene crosscutting veins and overgrowths although stable isotope data suggest a mixed magmatic meteoric origin for this late stage alteration Only late jarosite veinlets 8 0 Ma associated with fine grained pseudocubic alunite have a supergene isotopic signature
CPC Concasseur hybride Application Coarse size reduction of hard medium hard and soft material lime stone dolomite magnesia salt coal clay oil shale etc Throughput up to5 500 mt/hr depending on material characteristic and particle size
Stoichiometric end member alunites of the general formula A Al 3 SO 4 2 OH 6 with A = Na K Rb H 3 O and NH 4 have been synthesized under hydrothermal conditions together with samples of the potassium oxonium solid solution series over the entire compositional range A basic gallium sulfate of the alunite type was also synthesized and compared with the oxonium alunite structure
Part H evolution of the Rodalquilar caldera complex and associated gold alunite deposits J J Rytuba 1 A Arribas Jr 2 C G Cunningham 3 E H McKee 1 M H Podwysocki 3 J G Smith 1 Rue de la Loi 200 B 1049 Brussels Belgium Received December 1989/Accepted August 3 1990 Abstract The Rodalquilar caldera complex is located in
The U S Bureau of Mines conducted laboratory studies on sulfuric acid H2S04 digestion of alunite KA1a S04 z OH 6 as a means for treating domestic deposits of this mineral Digesting alunite ore in boiling S04 at concentrations of 88 wt pct acid or higher breaks down the alunite and permits a con venient separation of potassium and aluminum
An experimental study was made of alunite stability relations at 200 to 380 C and 15 000 psi total pressure The invariant point for the assemblage alunite muscovite kaolinite or pyrophyllite quartz in terms of total molal H 2 SO 4 and K 2 SO 4 respectively is placed at 0 002 and 0 03 at 200 0 012 and 0 013 at 300 and 0 02 and 0 016 at 380 C
Filter type Compatible HIFI item Comments Oil filter SO 10052 Diesel oil filter SN 55429 Primary air filter SA 10377 X2 Hydraulic filter SH 54038 RESERVOIR/TANK
alunite and natroalunite In the solution environment alunite and natroalunite are able to form stably by the Al3 hydrolysis precipitation process at a temperature of 200 C a pH value of 0 4 and a reaction time of 5 h When Al3 was precipitated at a K/Al molar ratio of 1 the aluminum pre
Setting 200 mm Setting 250 mm Setting 320 mm MFP FRANTOIO PRIMARIO A MASCELLE PRIMARY JAW CRUSHER CONCASSEUR PRIMAIRE A MACHOIRES F Modello Model Modèle Peso Weight Réglage sortie mm Pezzatura max alim Max feeding size Piéce max alim mm Produzione Output Production t/h N giri Operating Speed Vitesse RPM Potenza Power Puissance